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DtBuCzB CAS-no-2170487-30-4

CAS NO.:2170487-30-4

MF: C46H49BN2                          MW: 640.71                      OLED-sublimed 

Synonyms: Indolo[3,2,1-de]indolo[3′,2′,1′:8,1][1,4]benzazaborino[2,3,4-kl]phenazaborine, 2,5,15,18-tetrakis(1,1-dimethylethyl)-;DtBuCzB;BCz-BN;2,6-Bis(3,6-di-tert-butyl-9H-carbazol-9-yl)boron;4,9,23,28-tetratert-butyl-13,19-diaza-1-boranonacyclo[16.12.1.12,6.119,26.07,12.014,31.020,25.013,33.030,32]tritriaconta-2,4,6(33),7(12),8,10,14(31),15,17,20(25),21,23,26(32),27,29-pentadecaene;Indolo[3,2,1-de]indolo[1′,2′,3′:1,8][1,4]benzazaborino[2,3,4-kl]phenazaborine, 2,5,15,18-tetrakis(1,1-dimethylethyl)-; 
 

Appearance White to yellow powder/crystals
Chemical formula C46H49BN2
Molecular weight 640.7 g/mol
Absorption* λmax 467nm (Toluene)
Fluorescence λem 481 nm (Toluene)
HOMO/LUMO HOMO = – 5.30 eV, LUMO = – 2.80 eV
Synonyms 2,5,15,18-Tetrakis(1,1-dimethylethyl)-indolo[3,2,1-de]indolo[3′,2′,1′:8,1][1,4]benzazaborino[2,3,4-kl]phenazaborine, BNCz, BCz-BN
Classification / Family Triphenylboron, Blue dopant, Multiresonance thermally activated delayed fluorescent (MR-TADF), Sublimed materials.
                                       Purity Sublimed >99.5% (HPLC)
                            Product manager                             Joy Wu;      Email: Joy@coreychem.com

 

DtBuCzB is a carbazole-based triphenylboron MR-TADF material. DtBuCzB has a skeleton structure of CzBN with four bulky peripheral tert-butyl side groups that are evenly distributed on the 3,6-positions of two carbazole rings. The extended π-conjugation generated intensified oscillator strength with narrow greenish blue emission at 481 nm, a FWHM of 22 nm, and a PLQY of 91% in dilute toluene solution. Red-shifted emission spectrum is observed in the corresponding OLED devices producing a high color purity emission at 488 nm, FWHM of 29 nm and maximum EQE of 21.6%.

CONTACT/Email address: Joy@coreychem.com

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