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Bis(4-tert-butylphenyl)iodonium chloride

CAS NO.:5421-53-4

Purity: 98%;

Commercialized mature products

Product Name Bis(4-tert-butylphenyl)iodonium chloride
Synonyms Bis(4-tert-butylphenyl)iodoniumchloride;NSC8994;Bis(tert-butylphenyl)IodoniumChloride;4,4′-Di-tert-butyldiphenyliodoniumchloride;Iodonium,bis[4-(1,1-dimethylethyl)pheny]-,chloride(PF);4,4′-Di-tert-(t-butylphenyl)IodoniumChloride;Iodonium,bis[4-(1,1-dimethylethyl)phenyl]-,chloride;InitiatorIntermediateI
CAS NO 5421-53-4
Purity 98% above
MF C20H26ClI
MW 428.77791
Contact selina@coreychem.com

🧪 1. Basic Information

  • Chemical name: Bis(4-tert-butylphenyl)iodonium chloride

  • Molecular formula: C₂₀H₂₆ClI

  • Molecular weight: 428.78

  • Appearance: White to light yellow crystalline powder

  • Chemical type: Diaryliodonium salt (onium compound)

  • Photochemical property: Easily decomposes under UV or visible light to generate reactive cations or radicals.


⚙️ 2. Main Functions and Mechanism

🧩 (1) Cationic Photoinitiator

This is the most common and important application.


Bis(4-tert-butylphenyl)iodonium chloride undergoes photolysis under UV or visible light to produce aryl radicals (Ar•) and strong acids (H⁺ or Lewis acids), which initiate cationic polymerization of epoxy resins, vinyl ethers, urethane monomers, and other systems.

Reaction scheme:

Ar2I+→hνAr•+ArI+H+Ar_2I^+ \xrightarrow{h\nu} Ar^• + ArI + H^+

Key features in UV-curable systems:

  • Fast polymerization rate

  • Low shrinkage during curing

  • Excellent transparency and bubble-free films

  • Less sensitive to humidity


(2) Photoacid Generator (PAG)

Acts as a source of strong acids upon exposure to light, enabling image formation or etching processes.


Widely used in:

  • Photoresists for microelectronics

  • Semiconductor lithography

  • Printed circuit boards (PCB)

  • Microfabrication and MEMS


🔬 (3) Hybrid Photoinitiator Systems

When combined with electron donors such as amines, thioethers, or acetone derivatives, it can form hybrid radical/cationic initiation systems.


This combination enhances curing efficiency and expands the absorption range, making it suitable for visible-light LED curing systems (365–405 nm).


🏭 3. Major Application Fields

Application Field Function / Use
UV-curable epoxy systems Initiates cationic polymerization of epoxy or vinyl ether monomers
Photoresists & electronic encapsulation Acts as a photoacid generator (PAG)
UV-curable inks and coatings Enables fast curing, high gloss, and excellent chemical resistance
3D printing resins (SLA/DLP) Improves accuracy, curing speed, and layer resolution
UV adhesives and optical resins Used for low-shrinkage, transparent bonding formulations
Security & anti-counterfeit inks Enhances photosensitivity and printing precision

⚠️ 4. Safety and Storage

  • Light-sensitive: store in a sealed, light-protected container.

  • Keep in a cool, dry, and ventilated area.

  • Avoid inhalation of powder; use gloves and eye protection during handling.


5. Summary

Bis(4-tert-butylphenyl)iodonium chloride is a high-efficiency cationic photoinitiator and photoacid generator (PAG).


It decomposes under UV or visible light to produce strong acids and active species that initiate polymerization or pattern formation.


It is widely used in UV-curable epoxy systems, photoresists, electronic encapsulation materials, 3D printing resins, and high-performance UV inks and coatings.

1KG per bag; Or package according to customer needs

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