2-(3-Bromophenoxy)-9-(4-(tert-butyl)pyridin-2-yl)-9H-carbazole CAS No.: 2448397-99-5 , this carbazole derivative is an essential synthetic intermediate for high-end organic optoelectronic materials. Owing to its unique structural characteristics, it is widely utilized in the research of OLED materials and medicinal chemistry.
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📋Basic information:
- Chemical name: 2-(3-Bromophenoxy)-9-(4-(tert-butyl)pyridin-2-yl)-9H-carbazole
- CAS No.: 2448397-99-5
- Molecular Formula: C27H23BrN2O
- Molecular Weight: 471.39
📌Specification:
| Appearance: | White powder |
| Purity: | ≥98% |
| Density : | 1.30±0.1 g/cm3(Predicted) |
| Package: | 1KG/Bag, 5kg/Bag;or as per customer request |
| Storage: | Store in cool & dry place. |
🧩Application of 2-(3-Bromophenoxy)-9-(4-(tert-butyl)pyridin-2-yl)-9H-carbazole CAS No.: 2448397-99-5
I. Core Applications
II. Specific Application Scenarios
1. Synthesis of OLED (Organic Light-Emitting Diode) Materials
- Hole Transport Layer (HTL) Intermediate: The carbazole moiety features strong electron-donating properties, while the pyridine moiety exhibits weak electron-withdrawing properties. This facilitates hole injection and transport, and reduces the driving voltage of devices.
- Host/Dopant Matrix for Emissive Layer (EML): The D-A structure can modulate the band gap and emission color (mainly blue and green), improving device efficiency and stability.
- Component for Electron Blocking Layer (EBL): The tert-butylpyridine group enhances electron blocking capability and minimizes loss caused by carrier recombination.
2. Organic Photovoltaics (OPV) and Photodetection
It is applied to synthesize donor-acceptor conjugated polymers for the active layer and interfacial layer of organic solar cells, which improves light absorption and charge separation efficiency.
It can also be used to prepare sensitive layer materials for photodetectors, realizing optical signal conversion by taking advantage of the photoresponse properties of carbazole.
3. Organic Synthesis & Pharmaceutical Intermediates
IV. Structural Advantages
- Carbazole ring: High hole mobility and excellent thermal stability (high glass transition temperature, Tg).
- tert-Butylpyridine: Improves solubility, enhances electron affinity and stabilizes molecular configuration.
- m-Bromophenoxy group: High reactivity for easy derivatization; moderate steric hindrance inhibits molecular aggregation.
V. Common Downstream Derivatives
- OLED hole transport materials: N-phenylcarbazole derivatives, pyridocarbazole derivatives, etc.
- Thermally Activated Delayed Fluorescence (TADF) materials: The D-A structure enables efficient utilization of excitons.
- Organic semiconductor polymers: Applied in flexible electronics and printed electronic devices.
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